Dissipation and decontamination behaviour of a ready mix fungicide (azoxystrobin + difenoconazole) in tomato

dc.contributor.advisorSushil
dc.contributor.authorGodara, Rajni
dc.date.accessioned2019-11-21T06:57:35Z
dc.date.available2019-11-21T06:57:35Z
dc.date.issued2019
dc.description.abstractDissipation and decontamination behaviour of a ready mix fungicide (azoxystrobin + difenoconazole) was studied in tomato fruits and soil (at harvest). For this field experiments were carried out at research farm department of Entomology, CCS Harayana Agricultural University, Hisar. Tomato variety HS-102 was grown during the kharif season. For laboratory work, samples were collected at 0 (1 hr after application), 1, 3, 5, 7, 10 and 15 days after treatment, exclusively on random basis. The sample preparation method involving extraction with acetone provided 81.25 to 99.09 per cent recoveries for both the pesticides with precision RSD within 5-9% estimated at the limits of quantification (LOQ for azoxystrobin was 0.01 mg kg-1 and for difenoconazole it was 0.05 mg kg-1) and higher fortification levels. To study dissipation kinetics, the ready-mix fungicide was sprayed at dosage of 1 mL/L (single dose) and 2 mL/L (double dose). The residues were analysed on gas chromatograph equipped with electron capture detector (ECD). The dissipation kinetics followed first order kinetics with half-lives of 3-5 days for azoxystrobin and 1-3 days for difenoconazole. Decontamination of acquired residues by various culinary processes was quite efficient in minimising the residue load of both the fungicides. Maximum reduction was observed in case of washing followed by peeling (>75%) then washing followed by boiling (> 50%) and finally by washing with tap water (>30%). The residues of azoxystrobin and difenoconazole were confined mostly in the tomato peel. So peeled tomatoes are almost free from contamination of these fungicides and are safe for human beings.en_US
dc.identifier.urihttp://krishikosh.egranth.ac.in/handle/1/5810135868
dc.keywordsReady-mix, difenoconazole, azoxystrobin, limit of quantification, RSD, half-lives, decontamination and postharvest interval (PHI)en_US
dc.language.isoenen_US
dc.publisherCCSHAUen_US
dc.subChemistryen_US
dc.subjectnullen_US
dc.themeDissipation and decontamination behaviour of a ready mix fungicide (azoxystrobin + difenoconazole) in tomatoen_US
dc.these.typeM.Scen_US
dc.titleDissipation and decontamination behaviour of a ready mix fungicide (azoxystrobin + difenoconazole) in tomatoen_US
dc.typeThesisen_US
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