Evaluation of multi-nutrient extractants for determination of available P, K and micronutrient cations for soil analysis in Himachal Pradesh

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Date
2015-08-14
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CSHHPKV Palampur
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Multi-nutrient extractants offer alternative for conventional methods as more nutrients can be extracted in one go. However, the suitability and accuracy of such extractants for the determination of available nutrients must be verified. Therefore, sixty soil samples (0-0.15 m depth) collected randomly from different districts of Himachal Pradesh were used to evaluate the efficiency of AB-DTPA and AAAc-EDTA in comparison to their standard methods for P, K and micronutrient cations. Soil pH (1:2.5), EC (µS cm-1 ), OC (g kg-1 ), textural class, and CEC (cmol (p+ ) kg-1 ) soil under study ranged from 5.67-7.56, 61-695, 2.8-27.7, sandy loam to clay loam and 4.1- 15.0, respectively. Available P (kg ha-1 ) extracted by four methods viz., Olsen P, Bray P1, AB-DTPA P and AAAc-EDTA P varied from 7.8-44.3, 9.5-61.1, 6.5-38.8, 10.5- 52.1; available K (kg ha-1 ) extracted by three methods viz., NH4OAc, AB-DTPA and AAAc-EDTA ranged from 103.6-372.3, 86.6-364.9 and 74.6-362.5. Likewise, DTPA, AB-DTPA and AAAc-EDTA extractable contents of Cu, Fe, Zn and Mn ranged from 0.3-5.8, 1.0-6.3 and 1.2-5.0; 3.9-42.2, 8.1-58.8 and 7.3-32.7; 0.2-6.6, 0.3-6.7 and 3.3- 26.2, 5.1-27.2 and 7.7-38.3, respectively. Bray P1 method of phosphorus determination extracted more amount of available P followed by AAAc-EDTA, Olsen and AB-DTPA methods. Likewise NH4OAc extracted more K followed by AB-DTPA and AAAc-EDTA. In case of micronutrients cations, AB-DTPA in general, extracted more amounts as compared to DTPA alone. Overall, phosphorus showed highly significant correlations with physico-chemical properties. Among methods of extraction for P, AAAc-EDTA showed higher correlation with the standard method (Olsen P) of determination. Available K contents determined by AB-DTPA and AAAc-EDTA were well correlated with standard method (NH4OAc) however; AAAc-EDTA had higher correlation with AB-DTPA method for K extractability. In case of micronutrients, all the methods correlated positively and significantly with each other Highest significant correlations were observed between AB-DTPA and DTPA for Cu, Fe and Zn. However, in case of Mn, the highest correlation was observed between AB-DTPA and AAAc-EDTA. Both, AB-DTPA and AAAc-EDTA methods were more economical compared to the conventional methods.
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