ASSESSMENT OF ZINC USE EFFICIENCY IN MAIZE-MAIZE CROPPING SEQUENCE

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2022
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A field experiment was conducted at Krishi Vigyan Kendra, Jorhat farm, Kaliapani, Teok, Assam Agricultural University during 2018-19 and 2019-20 to study the influence of zinc fertilization on zinc fractions in soil, its relationship with important soil properties, yield, nutrient uptake and zinc use efficiency in maize-maize cropping sequence. The experiment was laid down in a randomized block design (RBD) with twelve treatments consisted of zinc applied as soil with or without foliar application through zinc sulphate and zinc oxide nano particle (ZnO NPs). Distribution of different zinc fractions in soil were assessed after harvest of each crop in the sequence. Perusal of experimental findings revealed that zinc fertilization had a significant influence on different zinc fractions in soil during both the years under investigation. The study revealed that among the zinc treatments, soil application of Zn @ 3.75 kg ha-1 in combination with foliar application of 500 ppm ZnO NPs exhibited the highest water soluble plus exchangeable-Zn content of 1.10 mg kg-1 in soil. The highest concentration of complexed-Zn (2.95 mg kg-1), amorphous sesquioxide-bound- Zn (4.11 mg kg-1), crystalline sesquioxide-bound-Zn (3.76 mg kg-1), residual-Zn (125.65 mg kg-1) and total-Zn (137.33 mg kg-1) were recorded in the treatment receiving soil application of Zn @ 7.5 kg ha-1. Among the zinc fractions studied, the concentration and percent contribution of water soluble plus exchangeable-Zn to total-Zn was the lowest while residual-Zn fraction contributed the highest to the total soil zinc pool. Path coefficient analysis showed that the water soluble plus exchangeable-Zn had the highest contribution towards the DTPA extractable-Zn in soil. The distribution of different zinc fractions at post-harvest soil was found in the following order: water soluble plus exchangeable-Zn < complexed-Zn < crystalline sesquioxide bound-Zn < amorphous sesquioxide bound-Zn < residual-Zn. All the fractions of zinc were found to be significantly and positively correlation with each other indicating existence of dynamic equilibrium of zinc in soil. Zinc fertilization exerted a significant influence on available nutrient status of soil. The highest available nitrogen content of 182.50 kg ha-1 was found in the treatment receiving soil application of Zn @ 3.75 kg ha-1 in combination with foliar application of 500 ppm ZnO NPs. The available phosphorus content in soil was decreased with zinc fertilization and thus, soil application of Zn @ 7.5 kg ha-1 recorded the lowest available phosphorus content of 19.45 kg ha-1, while the highest phosphorus content of 23.74 kg ha-1 was recorded in the control. However, no significant influence of zinc fertilization on available potassium, exchangeable calcium and exchangeable magnesium content in the post-harvest soils were observed. The highest available sulphur content of 25.50 kg ha-1 was registered in the treatment receiving soil application of Zn @ 7.5 kg ha-1. In respect of content of available micronutrients in soil, the DTPA extractable Fe, Cu and Mn content in soil were decreased with Zn fertilization and the highest content of DTPA extractable Fe (37.38 mg kg-1), Cu (0.42 mg kg-1) and Mn (9.26 mg kg-1) in soil was recorded in the control treatment, whereas, the lowest content was found in the treatment receiving Zn @ 7.5 kg ha-1. Application of 500 ppm ZnO NPs as foliar with soil application of Zn @ 3.75 kg ha-1 recorded significantly the highest DTPA extractable Zn content of 1.33 mg kg-1 in the post harvest soil. The study also revealed that zinc fertilization significantly influenced the grain and stover yield of maize. Perusal of pooled data indicated that among the zinc treatments, combined application of 500 ppm ZnO NPs as foliar with soil application of Zn @ 1.25 kg ha-1 registered the highest grain yield (65.04 q ha-1), stover yield (80.39 q ha-1) and harvest index (46.95%) in maize- maize sequence. Zinc fertilization exhibited a significant influence on uptake of major as well as micronutrients by maize. The highest uptake of nitrogen, potassium, calcium and magnesium by maize crops were recorded in the treatment receiving soil application of Zn @ 1.25 kg ha-1 in combination with 500 ppm ZnO NPs as foliar. The highest uptake of phosphorus by grain (14.81 kg ha-1) and stover (18.22 kg ha-1) was recorded in the treatment receiving 500 ppm ZnO NPs as foliar whereas, the highest sulphur uptake by grain (9.95 kg ha-1) and stover (11.72 kg ha-1) was found in the treatment receiving combined application of 500 ppm ZnO NPs as foliar with soil application of Zn @ 3.75 kg ha-1. Among the micronutrients, the highest uptake of Fe (214.56 g ha-1), Cu (31.99 g ha-1), Mn (56.33 g ha-1) and Zn (156.36 g ha-1) by maize grain was found in the treatment receiving combined application of 500 ppm ZnO NPs as foliar with soil application of Zn @ 1.25 kg ha-1. The highest uptake of Fe (846.24 g ha-1), Cu (45.99 g ha-1), Mn (248.57 g ha-1) and Zn (279.58 g ha-1) by maize stover was also found in the same treatment. Analysis of pooled data indicated that method of zinc fertilization had significant influence on zinc use efficiency by maize. The highest agronomic efficiency (2382.51 kg kg-1), apparent recovery efficiency (36.88%), zinc utilization efficiency (4067.44 kg kg-1) and partial factor productivity (16913.19 kg kg-1) was recorded in the treatment receiving foliar application of 500 ppm ZnO NPs. The highest physiological efficiency (12816.13 kg kg-1), agro physiological efficiency (7567.77 kg kg-1) was recorded in the treatment receiving combined application of 500 ppm ZnO NPs as foliar with soil application of Zn @ 1.25 kg ha-1. Cost benefit analysis revealed that among different treatment combinations, the highest gross return (Rs. 1,17,072.00), net return (Rs. 82,773.00) and highest B-C ratio (2.41) was registered in the treatment receiving 500 ppm ZnO NPs as foliar in combination with soil application of Zn @ 1.25 kg ha-1. Considering improvement of crop yield and economic return, combined application of 500 ppm ZnO NPs as foliar with soil application of Zn @ 1.25 kg ha-1 was found to be superior over other treatments
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