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Open Access
Partial substitution of muriate of potash by common salt for cassava (Manihot esculenta crantz) in oxisols of Kerala
(Department of Soil Science & Agricultural Chemistry, College of Agriculture, Vellayani, 1995) Sudharmai Devi, C R; KAU; Padmaja, P
Field experiments were carried out in the College of Agriculture, Vellayani during 1991 to 1994 to study the possibility and extent of substitution of K of Muriate of Potash with the Na of common salt in Cassava variety M4 used as the test crop. Substitution of K was tried at 4 levels viz. 25, 50, 75 and 100 per cent of the recommended dose. Muriate of potash, replaced by wood ash and a combination of KHCO3 and NaHCO3 (eliminating chlorine source) also were included in the experiment. Plant growth characteristics like plant height and number of leaves did not vary significantly as a result of substitution. The maximum LAI was observed in the case of 50% K as MOP + 50% Na as CS treatment at all the growth stages. An increase in chlorophyll content was observed with NaCl substitution. In the early growth stages there was no significant variation in the production of roots, but at the later stages there was significant difference in this aspect. The root volume at 2 MAP varied significantly between treatments. In general, there was an increase in total weight of plant with NaCI substitution upto 50% and thereafter a decrease with higher levels of substitution, at all growth stages. Significant treatment difference could be observed in tuber yield in both the years of the experiment. T3 (50% MOP +50% CS) registered the highest tuber yield and T5 the lowest. The bulking rate and Utilisation Index also differed significantly among treatments. The cooking quality of the tubers from T3 was as good as that of T1. Significant differences could be observed in total sugars, reducing sugars and sucrose content of fresh tubers under different treatments. With increasing levels of substitution, the content of total sugars increased. Sucrose content was found to increase with Na application upto 75% substitution of K by Na. Significant variation was observed in the crude protein, total amino acid and free amino acid content of tubers. Hydrocyanic acid, total phenols and crude fibre also differed significantly between treatments. The keeping quality studies revealed that tubers from T3 could be stored fresh up to 35th day in moist soil, whereas tubers from T1 could be stored only upto 12th day, without deterioration. Enzyme studies revealed significant difference in the activity of starch synthesising enzymes, but NRA at 6 MAP was not affected by different treatments. The uptake of N was highest in T1 and P and K in T3. Na uptake by T1 which received no Na was generally higher than other treatments receiving Na. Ca and Mg uptake also differed significantly between treatments. Changes in soil organic carbon, available P, available K and available Mg were statistically significant between treatments but that of Ca was significant only from 4 MAP onwards. Yield of tubers was positively and significantly correlated to the uptake of N, P, K, Na, Ca and Mg. Yield at harvest was positively and significantly correlated to the root weight and root volume and also to the bulking rate at 2 MAP. Path coefficient Analysis revealed that the maximum direct effect on yield was contributed by the drymatter of roots at 2 MAP. From the results, it can be concluded that in soils having low to medium status of K, the K of MOP can be substituted up to 50% by Na of commonsalt in cassava without affecting the quality and quantity of tubers.
Open Access
Status, availability and transformation of magnesium in acid soils of Kerala
(Department of Soil Science and Agricultural Chemistry, College of Horticulture, Vellanikkara, 1992) Prema, D; KAU; Jose, A I
The investigation consisted of four parts, namely (1) magnesium status of soils in Kerala (2) evaluation of laboratory indices of Mg availability (3) transformation of applied Mg in soil and (4) pattern of Mg uptake by banana from different sources at different levels. In Part I, one hundred and fifty surface samples were collected from all over the State of Kerala, to study the status of Mg as well as properties in relation to the behaviour of Mg in these soils. In part 2, some selected chemical agents were tried in twenty selected soils in order to evolve a suitable extractant for available Mg. In Part 3, two acid rice soils of Kerala namely, Karappadam and laterite were incubated at field capacity for a period of 180 days with and without the addition of magnesium sulphate, magnesite and dolomite at the rate of 1250, 2500 and 3750 kg MgO ha-1, to monitor the pattern of release of Mg from applied sources . Soil samples were drawn regularly at 15 days interval for the determination of available Mq and at 60 days interval for the determination of other important chemical properties. In Part 4, a field experiment of banana was conducted to study the response to applied Mg.
Open Access
Evaluation of acidity parameters in wetland soils of Kerala in relation to nutrient availability
(Department of Soil Science and Agricultural Chemistry, College of Agriculture, Vellayani, 1995) Usha, P B; KAU; Thomas, Varghese (Guide)
Soil acidity is a major constraint in the wetland rice soils of the tropics, which has got aggravated in recent times with the introduction of high yielding varieties of rice and intensive use of fertilizers. Kerala State, with its unique geomorphology, climate, hydrology and other environmental factors has led to the formation of wetland soils with specific physico-chemical and mineralogical properties. These soils sustain a major part of the rice tracts in the State. Attempts to bring these lands under rice cultivation brought to light the intensity and severity of soil acidity in the natural as well as manmade wetlands of this region. Though studies have started way back in 1920 to tackle the problem of acidity and associated nutritional factors, a detailed study to unveil the intricate physico- chemical phenomena contributing to acidity and an economic and efficient methodology to alleviate the severity of acidity has not been attempted so far. Hence a study has been conducted to evaluate the acidity parameters in relation to nutrient availability in wetland rice soils of Kerala. Twelve major wetland rice soils have been identified and classified according to Soil Taxonomy. They belong to natural as well as manmade wetlands, some of them having been indigenously classified and known by vernacular names like Kari land (acid peat), Karapadam (riverine alluvium), Kayal land (lake bed sediments), Pokkali lands (saline acid), Kole lands (flood plain), Kaipad lands (saline marsh). Twelve profile samples representing the major wetland rice soils comprising an area of 6 lakh ha have been subjected to detailed investigations for morphological, physical, chemical, mineralogical and electro chemical parameters. Surface samples, each at a radial distance of 5 km from the twelve locations were collected and subjected to detailed studies to evaluate the acidity parameters and acidity generating factors. Studies were also taken up to observe the kinetics of pH and nutrient availability under submergence for different intervals of time. A comparative study on the efficacy of different methods of estimating the lime requirement was also taken up. From the detailed investigations on the evaluation of acidity parameters of wetland rice soils of Kerala, it has been observed that there exists a great extent of variation with respect to the severity of acitive acidity in the profile and surface samples. Barring Chittoor soils which were slightly alkaline, all the soils under study were acidic in reaction. The profile and surface samples of Kari soil of Thakazhi and Pokkali soil of Njarakkal recorded the highest active acidity with a dry soil pH around 3.2. The rating of these surface soils on the basis of active acidity was Kari ≥ Pokkali > Karapadom > Vellayani > Kayal > Kole > Wyanad > Pattabi > Kaipad > Karamana > Kattampally. However, with respect to the mean values of pH of profile samples the rating was Kari > Pokkali > Kole > Kayal > Karapadom > Vellayani > Wyanad > Pattambi > Karamana > Kattampally > Kaipad. All the soils having high active acidity recorded high exchange, non-exchange and potential acidity with significant correlation between them. It was observed that major part of potential acidity of wetland soils of Kerala was constituted by non-exchange acidity due to the preponderance of Kaolinite clay minerals and high content of sesquioxides. Highest values for potential acidity were recorded by 18-30 cm. of Kari and surface layers of Pokkali profiles. Based on mean potential acidity of surface samples the soils could be rated as Kari > Pokkali > Kayal > Karapadom > Kole > Pattambi > Kattampally > Vellayani > Kaipad > Karamana > Wyanad. HOWEVER, WITH RESPECT TO PROFILE SAMPLES THE SEQUENCE WAS Kari > Pokkali > Kayal > Karapadom > Kole > Wyanad > Vellayani > Kattampally > Pattambi > Kaipad > Karamana. From the correlations worked out, it was found that aqueous pH (1:1) under dry condition was a more reliable parameter for evaluating acidity in the wetland rice soils of Kerala than pH under wet condition or in salt solution, because this parameter gave more significant correlations with acidity generating factors and available nutrients. It was also observed that available sulphur determined both active and potential acidity rather than total sulphur in sulphur rich soils. Path coefficient analysis of acidity contributing factors indicated that exchangeable aluminium was the best parameter for measurement of acidity, 87 per cent of variation in exchange acidity, 57 per cent of variation in non- exchange acidity and 63 per cent of variation in potential acidity. Comparison of different methods for calculating lime requirement proved the superiority of exchangeable aluminium method for the wetland rice soils of Kerala. Lower rates of lime requirement were observed by this method for Kattampally, Wyanad, Karamana, Pattambi and Kaipad soils. Studies on submergence showed that wetland rice soils of Vellayani, Karamana, Karapadom, Kole, Kaipad, Kattampally and Wyanad do not require lime to raise the Ph for rice cultivation because all these soils attain a pH value of 5.5 within two weeks of submergence. Consequently there was increased availability of nitrogen, phosphorus, potassium, calcium, magnesium, iron, manganese and silica. However, zinc, copper and sulphur were found to decrease by prolonged submergence. The detailed investigations conducted under this study on the evaluation of acidity parameters of wetland rice soils of Kerala in relation to nutrient availability have unveiled many intricate phenomena of soil acidity which are of great theoretical and practical significance. Contrary to the conventional concept that liming is a must in all acid soils, the present study underlines the cheap and easy method of alleviating acidity of certain wetland rice soils by optimum submergence and scientific water management. Further the study has revealed the feasibility of liming in soils with severe acidity based on specific methods of estimating the lime requirement of soils. However it is necessary to confirm the results of these in- vitro studies by adequate field studies in specific wetland rice tracts of Kerala State.
Open Access
Standardisation of plant part as an index of potassium status in banana, musa (AAB Group) nendran
(Department of Soil Science and Agricultural Chemistry, College of Agriculture, Vellayani, 1994) Sumam George; KAU; Padmaja, P
A field experiment in Musa (AAB group) Nendran, the most popular commercial fruit crop of Kerala was undertaken from August, 1991 to May, 1992 with seven graded levels of K as treatments replicated thrice. The soil, medium in N and P and high in K status belonged to the taxonomic class ‘loamy kaolinitic isohyperthermic aeric tropic fluvaquents’. The effects of higher levels of K on all important growth characters of the crop like height of pseudostem, girth of pseudostem at different heights from the ground level, total number of leaves, number of functional leaves, total leaf area, leaf area index and total dry matter production were more pronounced from the shooting stage of the crop after the plants had received the full dose of K supply. Uptake of major nutrients N, P and K showed increasing trend with increase in K supply. Uptake of Ca showed a negative relationship with increasing K application while Mg uptake showed an inconsistent pattern. Uptake of micronutrients Fe, Mn, Cu and Zn were maximum at K3 level of application (225 g K2O plant-1). Soil content of available K increased while exchangeable Ca and Mg contents decreased at higher levels of K supply. The maximum bunch yield of 26.18 t ha 1-which was significantly higher than all other treatments was recorded at K3 level (225 g k2O plant-1) This level also resulted in maximum values for all the yield attributing characters like number of hands bunch-1, number of finger bunch-1, weight of hand, length of finger, girth of finger and weight of finger. By adopting this recommendation a net fertilizer saving of 75g K2O plant-1 Can be achieved which is equivalent to 312.5 kg of muriate of potash costing Rs. 2000 at the present market rate. Over and above this, increase in yield obtained by doing so is 4500 kg ha-1. Additional income that could be generated by the way of sale of this at the rate of Rs. 8 kg-1 works out to Rs. 36000. Thus a total saving of Rs. 38000 ha-1 can be achieved by following the suggested recommendation. Path coefficient analysis of yield attributes showed that the character number of finger bunch-1 is having the maximum direct effect on yield followed by girth of fruit and weight of fruit. Quality characters of the fruit namely total and non reducing sugars, shelf life and flesh peel ratio showed significant and positive trend towards K nutrition. Correlation coefficient were worked out between bunch yield and important crop characters. Balance sheet of nutrients in soil after harvest of the crop was worked out to assess the final soil status of nutrients in relation to the initial status. Petiole of the third leaf up to shooting stage of the crop and that of the flag leaf there after was selected as the index of K status of the plant as the K content of the same was found to hold the maximum relationship with bunch yield at all the growth stages. The critical K levels in the petiole for maximum yield as well as maximum response to fertilizer application at each stage were determined which were found to be 1.30 per cent and 1.02 per cent respectively at early vegetative stage, 1.28 per cent and 1.06 per cent respectively at late vegetative stage, 1.80 per cent and 1.36 per cent respectively at shooting stage, 2.43 per cent and 1.98 per cent respectively at post shooting stage, 2.50 per cent and 1.80 per cent respectively at bunch maturation stage and 2.47 per cent and 1.80 per cent respectively at harvest stage. The critical K content in soil for economic yield worked out to 286.5 kg K2O ha-1 at early vegetative stage, 276.5 kg K2O ha-1 at late vegetative stage, 271.o kg K2O ha-1 at shooting stage, 239.o kg K2O ha-1 at post shooting stage, 245.0 kg K2O ha-1 at bunch maturation stage and 236.0 kg K2O ha-1 at harvest stage. Graphs were plotted relating petiole K content to soil K content at important growth stages of the crop based on quadratic regression models to provide information on soil K content at a particular stage if the petiole K content at that stage is known. Linear regression models were developed relating soil K content to fertilizer dose to find out the quantity of fertilizer to be applied to bring the soil level to the critical level.
Open Access
Electro-chemical properties of selected oxisols and ultisols of Kerala with special reference to charge characteristics and surface mineralogy
(Department of Soil Science and Agricultural Chemistry, College of Agriculture, Vellayani, 1992) Rajendran, P; KAU; Subramonia Iyer, R
A study has been conducted in seven selected profiles of Oxisols and Ultisols representing the important pedological units with a wide geographical distribution in the state to have a deeper insight in to the electro-chemical behaviour of these soils. A multipronged approach to the studies made are highlighted to enable a clear understanding of the achievements as against the major objectives and approaches made. A laboratory study with thirty six samples from seven profiles representing six Ultisols and one Oxisol has been carried out. Path coefficient analysis of important thirteen charge contributing factors against two parameters for measurement of charge and the inter-relationship of 15 soil characters show that organic matter5, clay %, R2 O3%, Alo% and Feo% are the major factors that control the surface charge behaviour of the soils. The factors studied explained only 55% and 48% of the variability of cation exchange and anion exchange respectively. Study of the distribution of the electric charges in the surface and sub- surface horizons of the soils was made by the means of potentiometric titrations and by measurement of adsorption of ions in the presence of varying concentration of electrolytes. The titration curves at different ionic strengths crossed at the common point intersection the zero-point of charge (zpc). Thus the electro-chemical behaviour of these soils was found to be similar to that exhibited by many metallic oxides in which the surface potential of reversible double layer is determined solely by the activity of potential determining ions, H+ and OH- in the bulk of the solution. The zpc for the surface horizons was found to be lower than the sub-surface and sub- surface horizons in all the soils studied. Soil to soil variation in zcp between surface and sub-surface horizons were more or less the same for all samples. Thus zcp can not be recommended as a taxonomic tool in soil classification to distinguish Oxisols from Ultisols. From known values of surface area and zpc of these soils, the values for net electric charge was calculated by the application of the Gouy- Chapman model of double layer and was found to obey the theory only at a critical electrolyte concentration. As the soils were found to be similar to that of constant potential systems, the charge distribution varied substan\tially with PH and electrolyte concentration. Direct measurement of adsorption of ions from solutions of KC1 NaCl and CaCl2 showed that the nature and valence of index cations also influenced the magnitude of the negative charges on the soils particles. On the basis of the influence of PHJ, electrolyte concentration and the valence of the counter-ions on the electric charges of the soils most of the conventional methods of ion-exchanged determinations using buffered electrolytes at high concentrations appears to be inappropriate for tropical soils. In a study for the evaluation of ion-exchange measurements it was found that the compulsive exchange methods is most suitable for the combined estimation of CEC and AEC. The traditional ammonium acetate method was found to give over estimations of CEC and thus very high values. Calcium chloride, 0.002 M was found to be equally effective but owing to the simplicity of the procedure, the former appeared better. The compulsive exchange method is free from the inherent defects of neutral normal ammonium acetate and hence would seem well suited for the Oxisols and Ultisols of Kerala. Although sesquioxidic components in combination with organic matter apparently dominate the charge properties of these soils, there was evidence from the titration curves to shows the presence of small amounts of clay minerals with permanent negative charge. This was confirmed by different methods and was found in good agreement with the estimated theoretical results. However under field conditions the expression of this constituent was minimum and the variable charge components such as Fe, al oxides certainly control the electro-chemical characteristics. In a separate experiment to find out the contribution of organic matter and sesquioxides towards exchanges properties of soils, it was observed that bout 64% of the negative sites and 8% of the positive was contributed from organic matter. Sesquioxides explained only 11% of the variablility in CECX and 22% of the variability in AEC. The combined effect of organic matter and R2O3 removal was highly significant with respect to CEC and AEC in all the soils studied. Mineralogical investigation revealed the presence of kaolinite as the dominant clay mineral. Appreciable amounts of smectities, quartz and gibbsite was also identified. The presence of smectities was not reflected in the CEC of any of the samples. Scanning electron micrographs did not give much information other than the presence of a thick coating of iron and amorphous materials over clay aggregates. The specific surface measured by ethylence glycol retention method invariably showed higher values than the determined values obtained for negative adsorption data. The specific surface determined closely followed the organic matter content of the samples inspite of the vertical increase in clay content with in profiles.
Open Access
Fate of carbofuran applied to the soil basin of black pepper
(Department of Soil science and Agricultural chemistry, College of Horticulture, Vellanikkara, 1996) Betty, Bastin; KAU; Wahid, P A
An investigation on the fate of carbofuran applied to the soil basin of black pepper (Piper nigrum L.) was conducted during 1992-1995 at the College of Horticulture, Vellanikkara. Laterite soils collected from the predominant pepper growing tracts of Kannur and Wayanad of Kerala state were used for the study. A field study was also conducted at the KADP farm attached to the College of Horticulture, Vellanikkara. The sorption of carbofuran in laterite soils and its persistence, influence of organic matter on the bio-availability of carbofuran, mobility of the insecticide in soil under field conditions and the effect of carbofuran on the growth of black pepper were assessed. The main findings of the study are given below. The sorption of insecticide in soil was found to be explained by Freundlich adsorption equation. The rates of sorption of carbofuran was not influenced by the organic matter contents . . An initial lag period was observed prior to carbofuran degradation in soil under laboratory conditions. Only one metabolite (3-hydroxycarbofuran) was detected as the product of degradation. The total content of 14C derived radioactivity was high in plants grown in soils with lowest organic matter content and vice versa. Hence, bioavailability of the insecticide is less in soils with high organic matter contents. So a discriminatory application of carbofuran is required depending on organic matter content of the soil. Thus for effective control of the pest in a soil with high organic matter content more quantity or carbofuran has to he applied than a soil with low content of organic matter. The residues of 14C-carbofuran absorbed plants left after HCl extraction, retained significant amounts of radioactivity which could be recovered following combustion. This indicated that determination of extraction efficiency by spiking or fortification of the samples with known quantities of insecticides would lead to overestimation of the recovery. The main metabolite of the carbofuran in the leaves was 3-hydroxy- carbofuran. Autoradiography of the bush pepper plants which was allowed to absorb 14C-carbofuran for 6 h showed that carbofuran was absorbed and translocated to the leaves and berry. Both carbofuran and hydroxycarbofuran were leached to the lower layers of soil (0-60 cm) during SW and NE monsoons. The content of hydroxycarbofuran was less than carbofuran in soils. In the foliage and berries carbofuran and the metabolite, 3-hydroxy- carbofuran accumulated. The content of hydroxycarbofuran was greater than that of carbofuran. As the harvesting time was delayed the content of residues also decreased. The early harvesting and use of immature berries may lead to more concentration of pesticide in the produce. This will lead to chances of more residue build-up in the human system.

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