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ThesisItem Open Access Biomineral enriched composts (BOKASHI) - a tool for enhancing nutrient availability and enzyme activity in Rhizosphere(Department of soil science and agricultural chemistry, college of agriculture, Vellayani, 2023-08-05) Shilpa, S.; KAU; Aprna, BBiomineral enriched composts (Bokashi) – A tool for enhancing nutrient availability and enzyme activity in rhizosphere The study entitled “Biomineral enriched composts (Bokashi) – A tool for enhancing nutrient availability and enzyme activity in rhizosphere” was carried out during 2020-22 in the Department of Soil Science and Agricultural Chemistry, College of Agriculture, Vellayani. The objective of the study was the production and evaluation of biomineral enriched composts for enhanced nutrient availability, yield of test crop (Bhindi) and enzyme activity in the rhizosphere. The study comprised of three parts viz., production and characterization of biomineral (Bokashi) composts from different organic sources, soil incubation study for evaluating the nutrient release pattern and field experiment for evaluating the performance of the biomineral enriched (Bokashi) compost. Bokashi composts were prepared from two substrates S1 (Aquatic weed Limnocharis flava) and S2 (Aquatic weed Limnocharis flava and banana pseudostem in 1:1 ratio). The substrates were allowed to ferment anaerobically using EM solution and the matured composts were enriched with three minerals like M1 (Calcium apatite), M2 (Epsom salt) and M3 (Sylvinite) at 2% rate in different combinations. The design followed was Completely Randomized Design with 14 treatments replicated thrice. The treatment combinations were T1 – Bokashi compost prepared from L.flava enriched with calcium apatite, T2 - Bokashi compost prepared from L.flava enriched with epsom salt, T3- Bokashi compost prepared from L.flava enriched with sylvinite, T4 –Bokashi compost prepared from 1:1 mixture of L.flava and banana pseudostem enriched with calcium apatite, T5 - Bokashi compost prepared from 1:1 mixture of L.flava and banana pseudostem enriched with epsom salt, T6 - Bokashi compost prepared from 1:1 mixture of L.flava and banana pseudostem enriched with sylvinite, T7- Bokashi compost prepared from L.flava enriched with calcium apatite and epsom salt, T8 - Bokashi compost prepared from L.flava enriched with epsom salt and sylvinite, T9 - Bokashi compost prepared from L.flava enriched with calcium apatite and sylvinite, T10 - Bokashi compost prepared from 1:1 mixture of L.flava and banana pseudostem enriched with calcium apatite and epsom salt, T11 - Bokashi compost prepared from 1:1 mixture of L.flava and banana pseudostem enriched with epsom salt and sylvinite, T12 - Bokashi compost prepared from 1:1 mixture of L.flava and banana pseudostem enriched with calcium apatite and sylvinite , T13 – Bokashi compost prepared from L.flava enriched with calcium apatite, epsom salt and sylvinite and T14 - Bokashi compost prepared from 1:1 mixture of L.flava and banana pseudostem enriched with calcium apatite, epsom salt and sylvinite. To all the treatments (T1 – T4) zeolite was added at a rate of 0.5%. The physico-chemical and biological properties of the produced composts were subjected to analysis. Based on the analysed parameters like major and minor nutrient, enzyme activity, C:N ratio, fertilizing index the best seven composts selected for incubation study and field experiment were T2, T7 , T10, T11, T12, T13 and T14. Among these T13 (Bokashi compost prepared from L.flava enriched with calcium apatite, epsom salt and sylvinite) was selected as the best compost with the highest values of nitrogen, phosphorous, micro nutrients and enzyme activity while the lowest value of C:N ratio was also reported by T13. In part 2 of the study a soil incubation was carried out to investigate the nutrient release pattern of selected composts. The design followed is CRD with 8 treatments which was replicated thrice. One kg soil was incubated at field capacity for four months. The treatments were T1 - Absolute control, T2 to T8 - selected best seven composts. The treatments were imposed at surface of the soil at 20 g kg-1 and thoroughly mixed. Soil sample was drawn at 1st, 4th, 8th, 12th and 16th week of incubation and analysed for organic carbon, P, K, Ca, Mg, S, Fe, Mn, Zn, Cu, dehydrogenase and cellulase activity. From the study, it was observed that nitrogen, phosphorous, potassium, calcium, sulphur, iron, copper, organic carbon and enzyme activity were found to be maximum at the 4th week of incubation. Zinc content was observed to be maximum during 12th week of incubation while magnesium content was highest during 16th week of incubation. Manganese availability was maximum during 8th week of incubation. In part 3 of the study a field experiment was conducted from February – May 2022 with Bhindi (var. Anjitha) as the main crop and Amaranthus (var. Arun) as the residual crop. In the field experiment 9 treatments were imposed viz. T1 - Absolute control, T2 to T8 – selected best seven composts and T9¬ - KAU POP recommendation. Analysis of postharvest soil for chemical properties revealed that the highest value of organic carbon (1.14 %) and nitrogen (319.86 kg ha-1) was recorded for T7. The highest value for available phosphorous (91.65 kg ha-1) was recorded for T8 which was on par with T6 (89.67 kg ha-1) and T7 (88.59 kg ha-1). The potassium content was found to be the highest for T6 (273.91 kg ha-1) which was on par with T8 (270.60 kg ha-1). T7 recorded the highest values of iron (48.54 mg kg-1), zinc (4.79 mg kg-1), copper (1.88 mg kg-1) and boron (0.832 mg kg-1). While manganese (25.62 mg kg-1) was reported to be the highest with regard to T8. The highest value of cellulase activity was recorded by T7 (45.53 µg glucose hydrolysed g-1 soil h-1) while T8 recorded the highest value of dehydrogenase activity (302.68 µg of TPF hydrolysed g-1 of soil 24 h-1). Analysis of rhizosphere soil showed the highest value of microbial biomass carbon (91.14 mg kg-1 soil), glomalin (14.27 mg g-1), humic acid (9.21 %), fulvic acid (9.98), fungi (5.52 log cfu g-1), actinomycetes (5.16 log cfu g-1) and soil respiration (4.17 mg CO2 g-1) for T7 while T8 recorded highest value for bacteria (7.90 log cfu g-1). T7 recorded the highest value for number of fruits per plant (30.67) which was on par with T5, T6, and T8. Fruit girth was found to be the highest for T7 (5.06 cm) which was on par with T6, T8 and T9. T7 also recorded the highest value for fruit length (23.81 cm), yield per plant (570.42 g) and total yield (21.05 t ha-1). The highest B: C ratio (2.26) was reported by T7. The highest yield of amaranthus (130.23 kg ha-1) was recorded for T7. From the study, T13 (Bokashi compost prepared from L.flava enriched with calcium apatite, epsom salt and sylvinite) was concluded as the best compost. T7 (Bokashi compost prepared from L. flava enriched with calcium apatite, epsom salt and sylvinite) and T8 (Bokashi compost prepared from the 1:1 mixture of L.flava and banana pseudostem enriched with calcium apatite, epsom salt and sylvinite) recorded the highest values for the available nutrient status during incubation period like nitrogen, phosphorous, magnesium, sulphur, iron, manganese, zinc, copper, organic carbon and enzyme activity. Considering both the soil parameters and yield parameters T7 (Bokashi compost prepared from L. flava enriched with calcium apatite, epsom salt and sylvinite) was recorded as the best treatment.ThesisItem Open Access Carrier based slow release fertilizer formulations for sustained nutrient release and enhanced crop production(Department of soil science and agricultural chemistry, Vellayani, 2023-08-10) Farha, M K.; KAU; Gladis, RThe study entitled “Carrier based slow release fertilizer formulations for sustained nutrient release and enhanced crop production” was conducted at the Department of Soil Science, College of Agriculture, Vellayani during the year 2022. In this study slow release fertilizer formulations were prepared, characterized and investigated for its nutrient release characteristics through leaching experiment with soil column and incubation study. Based on the stability and sustained release of nutrients throughout the leaching and incubation study, best formulations were selected and evaluated. A pot culture experiment was conducted in a completely randomized design replicated thrice using chilli variety Vellayani Athulya as test crop and evaluated the effect of slow release fertilizer formulations on nutrient availability, uptake, use efficiency, yield and quality of chilli. Carrier based slow release fertilizer formulations containing major, secondary and micro nutrients were prepared using compatible fertilizer sources (urea, rajphos, muriate of potash, phosphogypsum, magnesium sulphate, zinc sulphate and borax), carrier materials (zeolite, humic acid, charcoal, chitosan and nano zeolite) and binding/stabilizing agent carboxy methyl cellulose (CMC). The slow release fertilizer pellets prepared were, T1 - Fertilizer mix: Zeolite+ CMC (1:1), T2 - Fertilizer mix: Zeolite+ CMC (1:0.5), T3 - Fertilizer mix: humic acid+ CMC (1:1), T4 - Fertilizer mix: humic acid+ CMC (1:0.5), T5 - Fertilizer mix: charcoal+ CMC (1:1), T6 - Fertilizer mix: charcoal+ CMC (1:0.5), T7 - Fertilizer mix: chitosan+ CMC (1:1), T8 - Fertilizer mix: chitosan+ CMC (1:0.5), T9 - Fertilizer mix: nano zeolite+ CMC (1:1), T10- Fertilizer mix: nano zeolite+ CMC (1:0.5). The pellets prepared were found to be stable, disintegration time 9-13 hours, moisture 5.75- 8.68 %, pH 6.37- 6.90, EC 17.25- 23.17 dSm-1 , bulk density 0.5-0.58 Mg m-3 and weight 4.0- 4.5 g. They contained 8.21 to 9.02 % nitrogen, 5.36 to 5.76 % phosphorus, 3.0 to 3.50% potassium, 5.40 to 5.68 % calcium, 2.01 to 2.86 % magnesium, 4.10 to 5.30 % sulphur , 1.2 to 1.6 % zinc and 0.17 to 0.23 % boron. A soil column experiment was conducted for two weeks to study the nutrient leaching and to confirm the slow release tendency of formulations. The results showed a gradual increase in the release of nutrients from 2 to 14 days of leachate collected from slow release formulations while, fertilizer mix alone showed increasing trend initially and later decreased. A laboratory incubation study was carried out to investigate the nutrient release patterns of the formulations after addition to soil. The results revealed that the pH of soil remained acidic (5.30- 6.17) throughout the incubation period and the EC was found to be increasing from 0.11- 1.45 dSm-1 . The release of nutrients in soil was found to be increasing gradually from 0 to 90 days of incubation with maximum concentration was observed on 90th day for all the nutrients. Based on the stability of pellets and the release of nutrients throughout the leaching and incubation experiment three promising formulations were selected for the pot culture experiment. They were, T2 (FM: Z+CMC 1:0.5), T4 (FM:HA+CMC 1:0.5) and T5 (FM: CC+CMC 1:1) . The treatments of pot culture experiment were T1 -100% RDF as SRF 1 (FM: Z+ CMC -1:0.5) applied as basal,T2 -100% RDF as SRF 1 (FM: Z+ CMC -1:0.5) applied in two splits (basal & 1 MAP), T3 -75% RDF as SRF 1 (FM: Z+ CMC -1:0.5) applied as basal, T4 -75% RDF as SRF 1 (FM: Z+ CMC -1:0.5) applied in two splits (basal & 1 MAP), T5 -100% RDF as SRF 2 (FM: HA+ CMC -1:0.5) appliedas basal, T6 -100% RDF as SRF 2 (FM: HA+ CMC -1:0.5) applied in two splits (basal & 1 MAP), T7-75% RDF as SRF 2 (FM: HA+ CMC -1:0.5) applied as basal, T8 -75% RDF as SRF 2 (FM: HA+ CMC -1:0.5) applied in two splits (basal & 1 MAP), T9-100% RDF as SRF 3 (FM: CHAR+ CMC -1:1) applied as basal, T10-100% RDF as SRF 3 (FM: CHAR+ CMC -1:1) applied in two splits (basal & 1 MAP), T11-75% RDF as SRF 3 (FM: CHAR+ CMC -1:1) applied as basal, T12-75% RDF as SRF 3 (FM: CHAR+ CMC -1:1) applied in two splits (basal & 1 MAP), T13-Soil test based POP recommendation, T14- Control (No fertilizers). The analysis of post harvest soil showed the highest content of available N (320.8 kgha-1 ), P (87.15 kgha-1 ), K (214.3 kgha-1 ), Ca (351.1 mg kg-1 ), Mg (106.5 mg kg-1 ), S (9.32 mg kg-1 ), Zn (4.25 mg kg-1 ) and B (0.46 mg kg-1 ) in T8 receiving 75% RDF as SRF 2 (FM: HA+ CMC -1:0.5) applied in two splits (basal & 1 MAP). With regard to nutrient content and uptake, the treatment T8 registered the highest value. The growth and yield parameters like plant height (56.52 cm), number of branches per plant (9.5), number of fruits per plant (56.70), fruit length (13.44 cm), fruit girth (6.89 cm), fruit weight (11.03), fruit yield (581.2g plant -1 ) and total dry matter production (89.07 g) were found to be the highest in T8. Quality parameters of chilli such as ascorbic acid and capsaicin content were also found to be the highest in T8.The fertilizer use efficiency, agronomic efficiency, apparent recovery of major nutrients and partial factor productivity were found to be the highest recorded in treatment T8.The highest B:C ratio of 2.41 was recorded by treatment T8. Slow release fertilizer formulations containing macro and micro nutrients can be prepared using compatible fertilizer materials (urea, rajphos, MOP, phosphogypsum, magnesium sulphate, zinc sulphate and borax), carrier agents(zeolite, humic acid, charcoal, chitosan and nanozeolite) and binding agent (CMC). The slow release fertilizer pellets were found to be superior with respect to stability, disintegration time, nutrient content and release of nutrients. From the results it can be concluded that the slow release fertilizer formulations containing fertilizer mix: humic acid+ CMC in the ratio of 1:0.5 applied at 75% RDF in two splits as basal & 1 MAP was able to significantly increase the yield, uptake of nutrients, NUE, B:C ratio and quality of chilliThesisItem Open Access Management of calcium, magnesium and boron deficiency for enhancing yield and quality in chilli (Capsicum annuum L.)(Department of Soil Science and Agricultural Chemistry, College of Agriculture ,Padanakkad, 2022-04-28) Anjitha K.; KAU; Sailaja kumari M SThe investigation entitled ‘Management of calcium, magnesium and boron deficiency for enhancing yield and quality in chilli’ was carried out at Instructional farm, Nileshwar, College of Agriculture Padannakkad, with an objective to develop nutrient management practices for mitigating calcium, magnesium and boron deficiency and to evaluate its effect on growth, yield and quality parameters. The field experiment was carried out during December 2020 to May 2021. The experiment was carried out with chilli variety Anugraha, in randomized block design with ten treatments and three replications. Treatment combinations were T1(KAU POP + lime (based on soil test)), T2 (T1 + 125 kg gypsum per hectare), T3 (T1 + 80 kg magnesium sulphate per hectare), T4 (T1 + 125 kg gypsum per hectare + 80 kg magnesium sulphate per hectare), T5 (T1 + foliar application of borax (0.2%)), T6 (T2 + foliar application of borax (0.2%)), T7 (T3 + foliar application of borax (0.2%)), T8 (T4 + foliar application of borax (0.2%)), T9 (KAU POP + dolomite (based on soil test)) and T10 (T9 + foliar application of borax (0.2%)). Soil application of amendments were done as a single dose and foliar nutrition was given four times in a 20 days interval. Analysis of experimental results showed that various treatments showed significant effect on growth characters, fruit quality parameters as well as nutrient content in both soil and plant, over KAU POP recommendation. Significant positive effect of treatments on plant root characters and total dry matter production was observed whereas plant height and days to 50% flowering were found to be non significant. Among the treatments, maximum tap root length (13.50 cm), root volume (23.23 cm3 ), root shoot ratio (0.16) and total dry matter production (2694.65 kg ha-1 ) were recorded in T8 (KAU POP + lime application based on soil test) +125 kg gypsum per hectare + 80 kg magnesium sulphate per hectare + foliar application of borax (0.2%). Various treatments showed significant influence on yield and yield attributes. Maximum fruit weight (37.16 g) and total fruit yield (4456.79 kg ha-1 ) was also observed in T8 and in case of fruit yield, it was significantly superior to all other treatments. Combined application of gypsum, magnesium sulphate and borax were effective and maximized fruit yield. 94 Soil analysis was carried out at flowering and harvest wherein, the treatments showed significant effect on soil pH, EC, available potassium, calcium, magnesium, sulphur, iron, manganese and zinc content whereas available nitrogen, phosphorus, copper and boron were not influenced by treatments. Addition of calcium and magnesium sources significantly increased available calcium and magnesium content in soil. Among the various treatments, the highest available calcium was recorded in T8 and was on par with T2, T6 and T4 at flowering. Highest available magnesium content was recorded in T9 and T10 at flowering and harvest respectively. Analysis of Index leaves at flowering and total plant analysis at harvest were carried out and it was found that plant nutrient content was significantly influenced by treatments. Significant effect of various treatments on plant nutrients except nitrogen and phosphorus was observed. Foliar application of borax significantly improved boron content in plants. Fruit quality parameters such as capsaicin, oleoresin, ascorbic acid and shelf life and total nutrient content were analysed and results showed significant positive response to treatments. Analysis of nutrient content in fruits showed that primary nutrients mainly, nitrogen and potassium, secondary nutrients and micronutrients in fruits were significantly influenced by various treatments. The treatment, T8 (KAU POP + lime based on soil test) +125 kg gypsum per hectare + 80 kg magnesium sulphate per hectare + foliar application of borax (0.2%)) recorded highest capsaicin (0.352 %), oleoresin (11.00 %), ascorbic acid (96.83 mg 100 g-1 ) and maximum shelf life (13.66 days) in chilli. The results obtained from the experiment revealed the significant influence of soil amendments over KAU POP recommendation and it can be concluded that combined application of gypsum, magnesium sulphate and borax was effective for increasing fruit yield and quality in chilliThesisItem Open Access Soil quality index and nutrient balance in rice-rice cropping system under long-term fertilizer experiment(Department of Soil Science and Agricultural Chemistry, College of Agriculture, Vellanikkara, 2021) Drishya, D S; KAU; Thulasi, VLong-term experiments provide the best possible platform for studying the changes in soil properties and processes, identifying emerging trends in nutrient imbalances and deficiencies and help to formulate future strategies for maintaining soil health and quality. The present study entitled “Soil quality index and nutrient balance in rice-rice cropping system under Long Term Fertilizer Experiment” was undertaken at RARS, Pattambi and College of Agriculture, Vellanikkara. The objectives were set out to estimate soil quality index and NPK balance in rice-rice cropping system as affected by nutrient management practices under Long Term Fertilizer Experiment. The Long Term Fertilizer Experiment (LTFE) in rice-rice cropping system maintained (since 1997) at RARS Pattambi has been laid out in RBD consists of 12 treatments viz.,T1 : 50 per cent NPK, T2 : 100 per cent NPK, T3 : 150 per cent NPK, T4 : 100 per cent NPK + 600 kg ha -1 CaCO3 , T5 : 100 per cent NPK, T6 : 100 per cent NP, T7 : 100 per cent N, T8 : 100 per cent NPK + Farm Yard Manure (FYM) @ 5 t ha -1 , T9 : 50 per cent NPK + FYM @ 5 t ha -1 , T10 : 100 per cent NPK + in situ growing of Sesbania aculeata, T11 : 50 per cent NPK + in situ growing of Sesbania aculeata and T12 : Absolute control (No fertilizer or manures). The soil samples from 0-15 cm depth were collected from the different treatments of LTFE after the harvest of Virippu crop, 2020 and were analysed for various physical, chemical and biological properties. Principal Component Analysis (PCA) was performed to arrive at the Minimum Data Set (MDS) and Soil Quality Index (SQI) was formulated for different nutrient management practices. Integrated nutrient management with FYM and in situ green manuring with daincha recorded higher grain and straw yields of rice. The increase in fertilizer load into the soil resulted in increase in yields while the omission of primary nutrients resulted as decline in yields. Integrated Nutrient Management practice (INM) of application of FYM along with 100 percent NPK had lower bulk density (1.17 Mg m-3 ) and higher water holding capacity (43.65 %), higher levels of available nutrients and enzyme activities in the soil. However, dehydrogenase activity did not follow the same trend as that of microbial biomass carbon in treatments wherein fertilizers alone were applied indicating the chances of shift in the microbial populations as a result of the long term application of nutrient management practices. Principal Component Analysis (PCA) was performed for 28 soil attributes to develop the MDS and SQI was formulated using non linear scoring method. The MDS included bulk density, porosity, soil pH, permanganate oxidizable carbon, available N, total N, available sulphur, microbial biomass carbon, acid phosphatase and aryl sulfatase activities. The SQI ranged from 1.82 to 3.01. The SQI declined in the order of: T8> T10 >T9> T11> T4> T3> T2= T1> T5> T6 >T7> T12. The highest SQI was observed in T8 where 100 per cent NPK and FYM were applied. When the dosage of fertilizers was increased from 50% to 100% NPK on integration with FYM, the SQI increased. The soil quality index of the INM treatments (55.50 to 62.11%) and lime incorporation (52.98%) were categorized under medium category as per the computed Relative SQI (RSQI) values. The virippu crop (2020) under LTFE maintained at RARS Pattambi was monitored and various inputs and outputs regarding primary nutrients were assessed for balance predictions using NUTMON toolbox. The NUTMON toolbox includes five inflows, viz., mineral fertilizers (IN1), manure (IN2), atmospheric deposition (IN3), biological N fixation (IN4), and sedimentation (IN5), and five outflows, viz., harvested product (OUT1), crop residues (OUT2), leaching (OUT3), gaseous losses (OUT4), and erosion (OUT5). Nutrient flows like fertilizers, manures, crop residues and harvested outputs were monitored and measured during the experiment. Other flows like nitrogen fixation, leaching, and erosion were estimated by means of regression models from the data related to climate and crop parameters. Available NPK content of soils, rice grain, straw, stubbles, weeds and all inputs were analysed and stored in background database. The data were fed into the data processing module of the NUTMON toolbox to arrive at the partial and total balance of N, P and K in the experimental soil. The total balance of N, P and K were found to decline in order of: T3>T7>T8>T6>T5>T2>T4>T10>T9>T1>T11>T12 for N, T3>T8>T6>T10>T2>T5>T4>T9>T1>T11>T12>T7 for P and T3>T2>T5>T8>T9>T10>T4>T11>T1>T12>T7>T6 for K Summarizing the results, integrated nutrient management with FYM and in situ green manuring with daincha recorded higher yield and available nutrients in the soil. The incorporation inorganic fertilizers with FYM, daincha and lime maintain the soil quality index in the long run while, SQI was poor in control, imbalanced nutrition as well as in treatments where only fertilizers were incorporated. The balance sheet of P establishes the need for maintenance dose of P fertilizers in rice-rice cropping system. The negative balance of N and K indicate the need for supplementing the nitrogen pool and the possibility of mining of K on long term intensive cropping, respectively. Further study should be focused on monitoring the soil quality index at regular intervals and analyzing the effect of nutrient management practices on microbial diversity in rhizosphere and phyllosphere.ThesisItem Open Access Evaluation of water hyacinth co- composts for nutrient retention in lateritic soil(Department of Soil Science and Agricultural Chemistry, College of Agriculture, Vellanikkara, 2021) Anisha, V A; KAU; Durga Devi, K MWater hyacinth is a serious menace in low land ecosystems and it’s spread has threatened water quality and aquatic life. Various biological, chemical and physical methods that have been employed to control the weed has yielded minimal results. Hence management through utilization is a viable strategy. It can be effectively utilized in many ways to support crop production. Co-composting has been proved as a promising technique for safe and quick disposal of the weed by utilizing the co-substrates viz., poultry manure, sawdust, biochar, glyricidia, paddy straw, dried leaves and cattle manure. As the weed accumulates N, P, K and other essential nutrients, compost made from water hyacinth can be utilized for improving soil fertility and crop production. Hence, the present investigation entitled “Evaluation of water hyacinth co-composts for nutrient retention in lateritic soil” was under taken in the Department of Soil Science and Agricultural Chemistry at College of Agriculture, Vellanikkara during 2020-2021. The objectives were; (i) To find out the suitable combination of water hyacinth and co-substrates for enhancing the quality of water hyacinth composts (ii) To assess the nutrient retention capacity of different co-composts in lateritic soil. Different co-substrates were collected from nearby areas and water hyacinth was collected from Kole lands of Thrissur. Water hyacinth and co-substrates were characterized prior to composting. Water hyacinth co-composts (vermi compost) were prepared using the aforesaid substrates in concrete tanks. The physical and chemical properties of the composting mixtures were recorded at 40 days interval starting from 20 days of composting until 100 days. The yield of water hyacinth co-composts was estimated and the various co-composts were characterized for their physical and chemical properties. Incubation study was conducted to evaluate the nutrient retention capacity of different water hyacinth co-composts in lateritic soil during December 2020 with eight treatments and three replications (soil+ 7 co-composts and soil alone as absolute control). The lateritic soil for study was collected from Instructional Farm, Vellanikkara and analysed for chemical properties. Compost amended soils were incubated for a period of 28 days and nutrient retention capacity (N, P, K, Ca, Mg, S, B, Zn) was estimated at 4 different time periods after incubation (7, 14, 21, 28 days). Data on characterization of co-substrates revealed that substrates vary in their chemical properties and nutrient content. Among the co-substrates, poultry manure possessed many favourable characteristics. Changes in physical and chemical properties of composting mixtures at different intervals indicated the progress of composting process and stage of compost maturity. All the co-substrates gave reasonably good yield of water hyacinth co-composts. A notable increase in compost yield to an extent of 159.7 per cent was realized in the biochar treatment. Addition of co-substrates improved the bulk density and porosity of water hyacinth co-composts. Application of co-substrates improved the pH of final compost. Highest increase was noticed in the treatment with paddy straw. Addition of paddy straw had significant adverse effect on the electrical conductivity of final co-compost (170.6 % increase in EC over water hyacinth sole treatment) and all the other treatments showed EC below maximum permissible limit for plant growth. The total carbon content of all the co-composts was higher than water hyacinth sole compost. Nitrogen content of the co-compost was improved to a greater extent by the application of paddy straw and poultry manure. Co-composts with sawdust, biochar and dried leaves had significantly lower quantity of nitrogen compared to water hyacinth sole compost. Glyricidia and poultry manure were highly effective in improving total phosphorus content of the co-compost. Total potassium content of water hyacinth compost was significantly improved with the addition of co-substrates like paddy straw and biochar, the extent of increase being 192 and 170 per cent, respectively. Carbon to nitrogen ratio of water hyacinth co-compost was significantly lowered by using poultry manure as a co-substrate. Addition of poultry manure improved all the three secondary nutrients viz., Ca, Mg and sulphur to a higher magnitude. No favourable effect was noticed on the boron content of co-compost by the addition of different co-substrates. However, Fe and Mn levels of final co-composts were considerably lower than the water hyacinth sole compost. This could be considered as a favourable effect of co-composting of water hyacinth with different substrates. Zinc content of the co-compost was significantly improved by the inclusion of co-substrate particularly with the use of poultry manure and dried leaves. Copper content of the co-compost was significantly higher with the addition of poultry manure as co-substate. The addition of co-compost to lateritic soil, improved retention of nutrients particularly nitrogen. The only exception was co-compost with paddy straw (0.9 per cent decrease in the nitrogen retention capacity). Irrespective of the treatments, cocompost retained all the phosphorus and boron present in the co-compost amended soil. The soil’s potassium, magnesium, sulphur and zinc retention capacity could be improved when amended with water hyacinth co-compost. In general, soil with biochar co-compost showed significantly high retention capacity with respect to plant nutrients particularly nitrogen. Further study should be focused on field experiments to test the agronomic efficiency of different water hyacinth co-composts, testing suitability of various crop residues and organic wastes as co-substrates and to derive suitable substrate combinations and ratios to eliminate the adverse effects of co-substrate on compost quality.ThesisItem Open Access Soil test crop response studies in cluster bean (Cyamopsis tetragonoloba L.) in lateritic soils of Kerala(Department of Soil Science and Agricultural Chemistry, College of Agriculture,Vellanikkara, 2022) Ayisha, V V; KAU; Rajalekshmi, KCluster bean, commonly known as guar, is a legume crop cultivated as a vegetable, green manure and forage crop. India is the leading producer of cluster bean in the world and accounts for around 80 per cent of global production. The generalised application of fertilizers by farmers result in under or over fertilization, lowering production and profitability while also polluting the environment. So the emphasis on soil test based balanced fertilizer recommendation has become more pertinent in the current scenario of high fertilizer costs and yield maximisation programmes. Hence, the investigation entitled “Soil test crop response studies in cluster bean (Cyamopsis tetragonoloba L.) in lateritic soils of Kerala” was undertaken. The study was conducted at College of Agriculture, Vellanikkara in lateritic soils (Ultisol) in the STCR field during 2020-2021 with the objective of developing soil test based fertilizer prescription equation for cluster bean using inorganic fertilizers alone and with the combined use of organic manures. A fertility gradient experiment was conducted to create soil fertility gradient in the field by applying graded doses of N, P and K fertilizers and raising fodder maize var. CO1. After the development of fertility gradient, the main STCR experiment was conducted in the same field with the test crop, cluster bean var. Pusa naubahar. The treatment structure consisted of four levels of nitrogen (0, 10, 20 and 40 kg ha-1 ), four levels of phosphorous (0, 30, 60 and 120 kg ha-1 ) and four levels of potassium (0, 40, 80 and 120 kg ha-1 ) along with three levels of FYM (0, 15 and 25 t ha-1 ). The basic parameters such as nutrient requirement (NR) and contributions of nutrients from soil (CS), fertilizer (CF) and FYM (COM) were computed from the field experimental data. The nutrient requirements (NR) for cluster bean were worked out as 0.68, 0.05 and 0.22 kg N, P2O5 and K2O to produce one quintal yield. The contributions from soil (CS) were estimated as 9.84, 2.29 and 1.99 per cent of N, P2O5 and K2O respectively. The contributions from fertilizer (CF) were calculated as 90.90, 3.29 and 10.82 per cent and that from FYM (COM) were 7.17, 1.92 and 2.96 per cent for N, P2O5 and K2O respectively. From the above basic data, fertilizer prescription equation for specific yield targets of cluster bean in the lateritic soils were derived as follows, NPK alone: FN = 0.74*T - 0.11*SN FP2O5 = 1.47*T – 1.59*SP FK2O = 2.05*T- 0.22*SK NPK + FYM (IPNS) FN = 0.74*T - 0.11*SN – 0.08*ON FP2O5 = 1.47*T – 1.59*SP – 1.34*OP FK2O = 2.05*T - 0.22*SK – 0.33*OK Where, FN, FP2O5 and FK2O = Fertilizer N, P2O5 and K2O in kg ha-1 T = Yield target in q ha-1 SN, SP and SK = STV for available N, P and K in kg ha-1 . ON, OP and OK = Amount of N, P and K supplied through FYM in kg ha-1 . The multiple regression model calibrated with yield as dependent variable and soil test results and inorganic fertilizer doses as independent variables had 62.5 per cent predictability. The yield of cluster bean increased with the application of NPK alone and IPNS viz. NPK plus FYM treatment and the magnitude of increase was higher under IPNS over NPK alone. The study is useful to adjust fertilizer doses based on yield target and available resources of organic manure with the farmers. The equations developed for cluster bean should be tested in places with similar agro climate and soil situations for validation.ThesisItem Open Access Approaches to assess chlorpyrifos degradation in northern laterite soils of Kasaragod (AEU 11)(Department of Soil Science and Agricultural Chemistry, College of Agriculture, Padanakkad, 2022) Arya, P R; KAU; Binitha, N KThe investigation on “Approaches to assess chlorpyrifos degradation in northern laterite soils of Kasaragod (AEU 11)” was undertaken with the objective to evaluate the impact of physical, chemical and biological methods on degradation of chlorpyrifos in laterite soils. The study was carried out during 2019 – 2021 at College of Agriculture, Padannakkad in two incubation experiments. The incubation experiment no. 1 was carried out to know the pattern and time required for degradation of chlorpyrifos in soil. Northern laterite soils (AEU 11) collected from Pilicode were selected for the study. Pot culture study was conducted in five pots filled with 10 kg soil and drenched with chlorpyrifos (20 EC) at the concentration of 2.5 ml/L. Soil was analyzed at weekly intervals and results from the incubation study showed that chlorpyrifos content was reduced to 34.76% within 60 days. Significant decrease on soil pH (2.29%) was noticed after the application of chlorpyrifos. Chloride and phosphate ions were increased during the incubation period due to release of these ions from the chlorpyrifos compound during the degradation process. Microbial biomass carbon (8.2%) in soil was reduced significantly. Based on the results and findings from the incubation experiment no.1, duration of incubation experiment no.2 was decided for 60 days. The incubation experiment no. 2 was carried out to assess the best method of degradation of chlorpyrifos in laterite soil. The experiment was laid out in CRD with 12 treatments and three replications. Physical, chemical and biological agents were applied and evaluated to study their effect on degradation of chlorpyrifos. The treatment combinations were control (T1), hydrogen peroxide-5% (T2), Fenton reagent -0.5% (T3), hydrogen peroxide-5% + Fenton reagent -0.5% (T4), Pseudomonas fluorescens (T5), Trichoderma viride (T6), Pseudomonas fluorescens + Trichoderma viride (T7), sunlight – 6hrs (T8), ultra violet – 4hrs (T9), sunlight – 6hrs + ultra violet – 4hrs (T10), soil under saturated condition at 5 cm level of submergence (T11) and soil under saturated condition at 5 cm level of submergence with azolla (T12) Results from the incubation study revealed that combination of Pseudomonas fluorescens + Trichoderma viride showed the highest rate (74.99%) of chlorpyrifos degradation followed by Pseudomonas fluorescens (69.94 %) and Trichoderma viride (66.35 %) within 60 days. Effect of chlorpyrifos application on chemical properties of soil was studied at biweekly intervals. Soil pH was found to be significantly decreased throughout the incubation period. Highest pH (5.09) was recorded in treatment T10 (sunlight + UV light) whereas lowest in T4 (4.93). Effect of treatments on chloride ions in soil were found to be non significant, however it was continuously increased throughout the incubation period. Phosphate ions in soil decreased significantly in the initial period followed by gradual increase in the phosphate ions in soil. In the 8th week, 106 T5 recorded the highest phosphate ions (31.80 mg kg-1 ) while T1 recorded the lowest phosphate ions (28.86 mg kg-1 ) in soil. The effect of treatment application on soil biological properties were studied and showed that chlorpyrifos has inhibitory effect on microbial biomass carbon, dehydrogenase, phosphatase and urease activities of the soil immediately after chlorpyrifos application but later restored the activities. The treatments that received biological agents were not much affected with respect to the biological properties of the soil. Biological treatments such as T5 recorded the highest dehydrogenase activity (11.74 µg TPF g-1 soil day-1 ) while the T6 recorded the highest phosphatase activity (17.06 µg PNP g-1 soil hr-1 ) of the soil. Treatment T7 recorded the highest microbial biomass carbon (99.15 µg g-1 ) and the urease activity (36.16 µg NH4 + -N g-1 soil hr-1 ) in soil. There was a significant effect with respect to the two treatments maintained under submergence. The leachate from the chlorpyrifos treated soils were analysed at biweekly intervals. Treatments showed significant effect on leachate of chlorpyrifos residue at sixth and eighth week intervals. Treatment T11 (2598.62 µg L-1 ) showed the highest degradation followed by T12 (3318.07 µg L-1 ). The growth of azolla was normal during the initial period, later decaying of azolla was noticed. Growth of azolla was inhibited under the chlorpyrifos treatment because it could not tolerate the residual effect of chlorpyrifos. The results from the investigation revealed that chlorpyrifos degradation using combination of Pseudomonas fluorescens + Trichoderma viride had the best potential to remove the residues of chlorpyrifos insecticide present in treated soils. Biological treatments are recorded as the prominent agents in chlorpyrifos degradation and also maintains the soil health. On account of these findings, we can recommend the use of biological agents in combination or alone, as an ideal approach for degradation of chlorpyrifos in laterite soilsThesisItem Open Access Assessment of soil quality in the post - flood scenario of AEU 9 in Pathanamthitta district of Kerala and generation of GIS maps(Department of Soil Science and Agricultural chemistry, College of Agriculture, Vellayani, 2021) Shafna, S H; KAU; Gladis, RA study entitled “Assessment of soil quality in the post-flood scenario of AEU 9 in Pathanamthitta district of Kerala and generation of GIS maps” was carried out during 2018-20 with the objective to evaluate the soil quality in the flood affected areas of AEU 9 of Pathanamthitta district, to work out the soil quality index and to generate maps of various soil attributes and quality indices using GIS techniques. Survey conducted to identify the flood affected areas in AEU 9 of Pathanamthitta district revealed that the flood affected panchayats includes Kaviyur, Thumbamon, Kulanada, Thottapuzhassery, Kallupara, Mezhuvely, Panthalam, Kozhanchery, Aranmula, and Mallapally. All these panchayats were severely affected by flood havoc and submergence that occurred in Manimala, Pamba and Achankovil rivers during August 2018. A total of seventy five geo referenced surface soil samples were collected from the flood affected panchayats and analyzed for various physical, chemical and biological attributes. Minimum data set of soil indicators for computing soil quality was selected using principal component analysis. The selected parameters were sand content, bulk density, available B, available S, available K, available Mn and organic carbon. Scores and weights were assigned to each selected indicator, and computed the soil quality index. GIS techniques were used to generate thematic maps of various soil attributes and soil quality indices. Sediment deposition was observed in all panchayats, while highest deposition of sand and silt were observed in Aranmula and Thumbamon panchayats. The flood did not cause much alteration in the soil texture of AEU 9 of pathanamthitta. The dominant textural class was loam. The particle density and bulk density of soil ranged from 2.07 to 2.45 and 0.87 to 1.76 Mg m -3 respectively. More than 89 per cent of the soils showed porosity in the range of 50 to 80 per cent. The soil moisture content ranged between 15.2 to 50.8 per cent. The water holding capacity and water stable aggregates ranged from 25.4 to 62.4 per cent and 38.6 to 68.5 per cent respectively. 137The electrical conductivity of soil ranged between 0.05 and 0.40 dS m -1 . Post flood soil showed an increase in the organic carbon status of the soil. Majority (95 %) of soil comes under medium and high organic carbon status after flood. About 54.7 per cent of the soils are medium in available N content. Available phosphorus content varied between 8.10 and 104 kg ha -1 with a mean of 31.9 kg ha -1 and available potassium varied between 78.7 and 493 kg ha -1 with a mean of 246 kgha -1 . The post flood soils are adequate in available sulphur (92 %) and deficient in boron status (100 %). The soil quality analysis revealed that majority of soils had high soil quality index (86.7%). Land quality index was very low in 64 % of soils while 32 % samples showed low land quality index. Nutrient index for nitrogen was low in most of the panchayats, medium and high for phosphorus, potassium and organic carbon. The results of the study revealed that most of the soil became strongly acidic after flood. Organic carbon, potassium, phosphorus and sulphur are high and medium status while nitrogen is low in most of the panchayats. Deficiency of calcium and magnesium increases after flood. The entire study area showed deficiency of boron. The results outline the need for regular liming to control soil acidity and alleviate calcium deficiency. It is also suggested to supplement magnesium and boron to improve soil quality.ThesisItem Open Access Assessment of soil quality in the post - flood scenario of AEU 9 in Pathanamthitta district of Kerala and generation of GIS maps(Department of Soil Science and Agricultural chemistry, College of Agriculture, Vellayani, 2021) Shafna, S H; KAU; Gladis, RA study entitled “Assessment of soil quality in the post-flood scenario of AEU 9 in Pathanamthitta district of Kerala and generation of GIS maps” was carried out during 2018-20 with the objective to evaluate the soil quality in the flood affected areas of AEU 9 of Pathanamthitta district, to work out the soil quality index and to generate maps of various soil attributes and quality indices using GIS techniques. Survey conducted to identify the flood affected areas in AEU 9 of Pathanamthitta district revealed that the flood affected panchayats includes Kaviyur, Thumbamon, Kulanada, Thottapuzhassery, Kallupara, Mezhuvely, Panthalam, Kozhanchery, Aranmula, and Mallapally. All these panchayats were severely affected by flood havoc and submergence that occurred in Manimala, Pamba and Achankovil rivers during August 2018. A total of seventy five geo referenced surface soil samples were collected from the flood affected panchayats and analyzed for various physical, chemical and biological attributes. Minimum data set of soil indicators for computing soil quality was selected using principal component analysis. The selected parameters were sand content, bulk density, available B, available S, available K, available Mn and organic carbon. Scores and weights were assigned to each selected indicator, and computed the soil quality index. GIS techniques were used to generate thematic maps of various soil attributes and soil quality indices. Sediment deposition was observed in all panchayats, while highest deposition of sand and silt were observed in Aranmula and Thumbamon panchayats. The flood did not cause much alteration in the soil texture of AEU 9 of pathanamthitta. The dominant textural class was loam. The particle density and bulk density of soil ranged from 2.07 to 2.45 and 0.87 to 1.76 Mg m -3 respectively. More than 89 per cent of the soils showed porosity in the range of 50 to 80 per cent. The soil moisture content ranged between 15.2 to 50.8 per cent. The water holding capacity and water stable aggregates ranged from 25.4 to 62.4 per cent and 38.6 to 68.5 per cent respectively. 137The electrical conductivity of soil ranged between 0.05 and 0.40 dS m -1 . Post flood soil showed an increase in the organic carbon status of the soil. Majority (95 %) of soil comes under medium and high organic carbon status after flood. About 54.7 per cent of the soils are medium in available N content. Available phosphorus content varied between 8.10 and 104 kg ha -1 with a mean of 31.9 kg ha -1 and available potassium varied between 78.7 and 493 kg ha -1 with a mean of 246 kgha -1 . The post flood soils are adequate in available sulphur (92 %) and deficient in boron status (100 %). The soil quality analysis revealed that majority of soils had high soil quality index (86.7%). Land quality index was very low in 64 % of soils while 32 % samples showed low land quality index. Nutrient index for nitrogen was low in most of the panchayats, medium and high for phosphorus, potassium and organic carbon. The results of the study revealed that most of the soil became strongly acidic after flood. Organic carbon, potassium, phosphorus and sulphur are high and medium status while nitrogen is low in most of the panchayats. Deficiency of calcium and magnesium increases after flood. The entire study area showed deficiency of boron. The results outline the need for regular liming to control soil acidity and alleviate calcium deficiency. It is also suggested to supplement magnesium and boron to improve soil quality.