Phukan, Ava RaniRoy, Reena2023-10-252023-10-252021https://krishikosh.egranth.ac.in/handle/1/5810199648Textile dyeing industries are one of the most polluted industries which createlots of problems for environmental pollution. The textile dyeing industry produces in large amount of production and release of waste water effluent. In the present study, activated carbons were prepared from almond, coconut, mustard, rice bran and sesame oil cakes. The powdered oil cakes were treated with 5% NaCl for 12 hours in the rotary shaker followed by chemical activation with 1 N H3PO4, 2.5 N H2SO4 and 2.5 N H3PO4 for 24 hours. The pyrolysis was performed at 300˚C for 2 hours. The ball milling technique was applied to reduce the particle size of the activated carbon. The integrated activated carbons were used for the color removal for acid and metal complex dye effluent from the wool dyeing unit. For dye effluent treatment different concentrations of adsorbent viz.,0.1%, 0.25%, 0.5% and 1.0% and time period 30, 60 and 90 minutes were taken respectively. The results showed that very small quantities (1.0 and 2.0%) of activated carbons were sufficient to remove around 92% color from the dye effluent. The particle size of the activated carbon was further reduced by ball milling in Pulverisette 6 for 1 hour.The characterization of activated carbon was synthesized such as FTIR, SEM, EDX, XRD, BET, bulk density, porosity, ash content, moisture content, pH, zero point charge (pzc), iodine number, methylene blue, particle size analysis, COD and BOD respectively. The activated carbon characterized by using scanning electron microscopy (SEM) revealed the small pore size with higher surface area that indicates lower absorbency. FTIR analysis also revealed the presence of various types of functional groups during different activation temperatures. From EDX analysis, a negligible quantity of Na, K and S in 2.5 N H3PO4 almond activated carbons and in 2.5 N H2SO4 almond activated carbons there was a negligible quantity of Mg, Si, P and C and other elements were present.The X-ray diffraction pattern of the 2.5 N H2SO4 and2.5 N H3PO4 almondwere recorded at peak 25˚ and 29˚ respectively, and indicated the presence of amorphous structure of the activated carbon with the diffraction pattern of (002).In BET analysis; the surface area, pore radius and pore volume of 2.5 N H3PO4 was recorded as 16.14m2/g, 0.85nm and 0.029cc/g and in 2.5 N H2SO4 almond, it was 7 recorded 64.28m2/g, 0.72nm and 0.040cc/g respectively. Bulk density 4.533g/cm3, porosity 4.500%, ash content 0.176%, moisture contents 0.040%, methylene blue 123.667mg/g, pH 6.180, zero point charge 4.140pzc, particle size 310.333nm, iodine number 22.067m2/g of 2.5 N H3PO4 almond (ball milling) activated carbon were recorded best compared to 1 N H3PO4 coconut (ball milling) and 2.5 N H3PO4 mustard (ball milling) activated carbon. The bulk density 5.233g/cm, porosity 3.633%, ash content 0.172%, moisture contents 0.071%, methylene blue 116.000mg/g, pH 6.973, zero point charge 6.460pzc, particle size 825.000nm, and iodine number 21.5333m2/g were also recorded best in 2.5 N H2SO4 almond (ball milling) activated carbon metal complex dye effluent compared to 2.5 N H3PO4 rice bran (ball milling) and 2.5 N H2SO4 sesame (ball milling) activated carbon. The good absorbency was recorded 0.107 at 2.0% concentration and 90 minutesof contact time in 2.5 N H3PO4 almond (ball milling) activated carbon acid dye effluent compared to 1 N H3PO4 coconut (ball milling) and 2.5 N H3PO4 mustard (ball milling) activated carbon. The pH and TDS of the effluent were recorded 4.523 and 2668.66mg/L, concentration 2.0% in 60 minutes, which were found to be best among the 1 N H3PO4 coconut (ball milling) and 2.5 N H3PO4 mustard (ball milling) activated carbon in acid dye effluent. The good absorbency was recorded 0.153 concentration 1.0% and 90 minutes of contact time in 2.5 N H2SO4 almond (ball milling) activated carbon metal complex dye effluent compared to 2.5 N H3PO4 rice bran (ball milling) and 2.5 N H2SO4sesame (ball milling) activated carbon. The pH and TDS of the effluent were recorded best in5.233 and 2219.33mg/L, concentration 1.0% at 90 and 30 minutes respectively in 2.5 N H2SO4 almond (ball milling) activated carbon metal complex dye effluent. Therefore, 2.5 N H3PO4 almond (ball milling) activated carbon acid dye and 2.5 N H2SO4 almond (ball milling) activated carbon metal complex dye effluent proved to be an excellent oil cake for preparation of activated carbon in the textile dye industry and can be used as an alternative source for wastewater treatment. Keywords: Activated carbon, oil cake, wastewater effluent, FTIR, SEM, XRD, TDSEnglishThesis