Study on microstructure and pozzolonic properties of fly ash-based geopolymer mortar containing nanometakaolin

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Date
2018
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Punjab Agricultural University, Ludhiana
Abstract
Geopolymerization is a process that can transform alumina-silica rich waste materials into valuable binding materials through alkali activation. Geopolymer binding materials are mainly composed of two components: a source material and alkaline activator liquid. The source material for geopolymer mortar and concrete should be rich in silica and alumina. In this study, fly ash-based geopolymer mortar was prepared by utilizing fly ash as a source material and the mixture of sodium hydroxide and sodium silicate as alkaline activator solution. The present experimental study shed a light on the fluctuations in compressive strength of fly ash-based geopolymer mortar by varying the molarity (M) of sodium hydroxide as 12M, 14M, 16M along with different proportions of nano-metakaolin (NMK) (0% to 10% @ 2% increment by weight of fly ash). The compressive strength was checked subsequently at curing ages of 3, 7, 14 and 28 days. X- ray diffraction test was performed on powder samples of fly ash, S1, S7, S13 and S15. The powder samples of S1, S7, S13 and S15 mix were collected from the remnants of geopolymer mortar specimens after 28 days compressive strength test. It has been observed that the increase in sodium hydroxide molarity and NMK proportion showed considerable improvement in compressive strength of geopolymer mortar at all curing ages. Further, it has been observed that optimum gain in compressive strength is at the 16M molarity of sodium hydroxide containing 4% proportion of NMK. XRD results are in conformity with compressive strength test results.
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